Alkylation of the Dimethylglyoximato Ligands in Reduced Cobaloxime
Silverman, R.B. and David Dolphin
Can. J. Chem.
Reaction of (pyridine)(bisdimethylglyoximato)cobalt(II) with MeOCH2Cl in deoxygenated dry benzene, gave preferential alkylation of the ligand rather than the Co, to give MeC(:NOH)CMe(:NOCH2OMe).