Pub No:
55
Title:
Reactions of Vinyl Ethers with Cobalamins and Cobaloximes
Authors:
Silverman, R.B. and David Dolphin
Journal:
J. Am. Chem. Soc.
Year:
1974
Pages:
96, 7094-7096
Abstract:
Experimental details for the previously reported reactions (B. B. Silverman and D. Dolphin, 1973) of cobaloximes and cobalamins with Et vinyl ether or (vinyloxy) ethanol to give (2,2-diethoxyethyl) or (1,3-dioxolan-2-ylmethyl) derivatives, are presented. A rationale for the existence of Co(III) π-complexes is discussed.

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