Pub No:
164
Title:
Catalytic Oxidation of Hydro-carbons Using Iodosylbenzene in the Presence of a Ruthenium(III) Porphyrin Complex
Authors:
Leung, T., James, B.R., and David Dolphin
Journal:
Inorg. Chim. Acta.
Year:
1983
Pages:
79(B7), 180
Abstract:
The ruthenium(III) octaethylporphyrin complex, Ru(OEP)(PPh3)Br (1), has been prepared by the oxidation of Ru(OEP)(PPh3)2 with excess bromine, and fully characterized by spectroscopic and crystallographic methods. CH2Cl2 solutions of 1 (5 10-3 M) containing iodosylbenzene (0.1 M) catalyze at 20 oC the oxidation of certain olefins and cyclohexane (0.220.5 M).

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